The Difference between N & C

In our last post we talked about what parylene was and it’s many benefits. However, we didn’t talk about the fact we use 2 different kinds of parylene, N, and C. 

What is Parylene?

Parylene is a common generic name for a unique series of polymers based on paraxylene. The parylenes are formed by the pyrolysis of a di-p-xylene (dimer) in a vacuum environment. This vapor is then deposited onto the room temperature item that’s within the vacuum chamber. The vapor phase deposition of the parylene polymer allows it to be formed as a continuous film which is truly conformal to the structure of the surface of the material upon which it is being deposited.

Conformal coatings are generally applied in a liquid phase by spraying, dipping, or brushing. Parylene materials form linear, highly-crystalline polymers that can be usefully produced only as coatings and films. The resulting film is thin and highly conformal, has no pinholes, can completely encapsulate a substrate to protect it from many conditions such as environmental attack, moisture, chemicals, fungus, dirt and dust.

Key Parylene Properties:

  • Fully biocompatible. Parylene has been FDA-approved (with USP XXII Class VI biocompatibility rating) and is safe for use within the human body. Parylene coatings protect a wide array of devices and components, including stents, pacemakers, defibrillators, hearing aids, tubes, elastomers, and more
  • Chemically inert. Parylene is chemically and biologically inert and stable, does not readily react with any other substance or chemical, and makes excellent barrier materials.
  • Non-toxic. Parylene is routinely used in medical and bio-medical applications.
  • Clean, clear, and sterile. Parylene does not promote the growth of biologics. Its surface is unsuitable for the proliferation of bacteria and other pathogens.
  • Exceptional electrical isolation. Parylene possesses exceptional electrical properties, notably its low dielectric constant and high dielectric strength.
  • Superior protection. Parylene films provide superior protection against moisture, chemicals, salt water, corrosion, fumes, gases and widely varying environmental conditions as well as being Mil-l-46058C approved.
  • Chemical resistance. Parylene resists attacks and is insoluble in all organic solvents and is resistant to and permeation by most solvents with the exception of aromatic hydrocarbons.
  • Dry lubricity. Parylene acts as a dry film lubricant, eliminating the need for liquid release agents. 
  • Excellent uniformity. The Parylene process is a controlled Chemical Vapor Deposition (CVD), where the film is deposited one molecule at a time, and its thickness is completely and truly uniform to the surface. 
  • Extremely lightweight. Parylene has minimal added mass making it extremely lightweight; very low outgassing
  • Pinhole-free coverage. Parylene provides strong, pinhole-free coverage for crevices, sharp edges, unusual shapes, and more.
  • No curing cycle. Parylene does not have a liquid phase. Therefore, it has no cure time.

Parylene N

Parylene N is a completely linear, highly crystalline material. Parylene N is a primary dielectric, exhibiting a very low dissipation factor, high dielectric strength, and a low dielectric constant invariant with frequency. It is able to penetrate crevices more effectively than Parylene C because of the higher level of molecular activity that occurs during the deposition.

Parylene C

Parylene C is produced from the same raw material (dimer) as Parylene N, modified only by the substitution of a chlorine atom for one of the aromatic hydrogens. Parylene C deposits on substrates at a faster rate than Parylene N and is an excellent barrier with a useful combination of electrical and physical properties, plus a very low permeability to moisture and corrosive gases.

Article Written by – Marketing Manager Emily Waterhouse

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